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A Green Procedure for the Oxidation of Benzyl Halides to Aromatic Aldehydes or Ketones in Aqueous Media
Authors:Pengwu Zheng  Li Yan  Xiujie Ji  Xuemin Duan
Affiliation:1. School of Pharmacy, Jiangxi Science and Technology Normal University , Nanchang, P. R. China zhengpw@126.com;3. School of Pharmacy, Jiangxi Science and Technology Normal University , Nanchang, P. R. China;4. School of Material Science and Engineering, Tianjin Polytechnic University , Tianjin, P. R. China
Abstract:
Green oxidation of benzyl halides to the corresponding aldehydes or ketones was achieved in aqueous media using trimethylamine N-oxide generated in situ from trimethylamine and H2O2. The yield of the reaction was excellent and the workup was simple.
Keywords:Aldehydes  benzyl halides  green oxidation  ketones  trimethylamine N-oxide
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