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Cyclohexenones Through Regioselective Addition of 1,3-Dicarbonyl Compounds to Terpenoid-Like Bischalcones
Authors:Esra Findik  Yakup Budak  Mustafa Ceylan
Affiliation:1. Department of Chemistry , Faculty of Arts and Sciences, Gaziosmanpasa University , Tokat, Turkey mceylan@gop.edu.tr;3. Department of Chemistry , Faculty of Arts and Sciences, Gaziosmanpasa University , Tokat, Turkey
Abstract:
Terpenoid-like bischalcones (3 and 4) were synthesized from the reaction of α- and β-ionones and benzaldehydes in excellent yields. The Michael addition of 1,3-dicarbonyl compounds to bischalcones (3 and 4) resulted in the formation of cyclohexenones derivatives (10a–d and 14a, b) via regioselective addition of 1,3-dicarbonyls and then cyclization.
Keywords:Cyclization  cyclohexenones  regioselective addition  terpenoid-like bischalcone
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