Cyclohexenones Through Regioselective Addition of 1,3-Dicarbonyl Compounds to Terpenoid-Like Bischalcones |
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Authors: | Esra Findik Yakup Budak Mustafa Ceylan |
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Affiliation: | 1. Department of Chemistry , Faculty of Arts and Sciences, Gaziosmanpasa University , Tokat, Turkey mceylan@gop.edu.tr;3. Department of Chemistry , Faculty of Arts and Sciences, Gaziosmanpasa University , Tokat, Turkey |
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Abstract: | Terpenoid-like bischalcones (3 and 4) were synthesized from the reaction of α- and β-ionones and benzaldehydes in excellent yields. The Michael addition of 1,3-dicarbonyl compounds to bischalcones (3 and 4) resulted in the formation of cyclohexenones derivatives (10a–d and 14a, b) via regioselective addition of 1,3-dicarbonyls and then cyclization. |
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Keywords: | Cyclization cyclohexenones regioselective addition terpenoid-like bischalcone |
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