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Synthesis and Metal Complex Formation of a Bis(terpyridine) Derivative with a Phenylacetylene Framework |
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| Authors: | Tomoyuki Tokizaki Takuya Toyoshima |
| Affiliation: | 1. Department of Biomolecular Science , Faculty of Science , Toho University , Chiba , Japan;2. Department of Biomolecular Science , Faculty of Science , Toho University , Chiba , Japan;3. Research Center for Materials with Integrated Properties , Toho University , Chiba , Japan |
| Abstract: | A new bis(terpyridine) derivative with a phenylacetylene framework was synthesized via a stepwise terpyridine construction strategy. The addition of ZnCl2 to a solution of the bis(terpyridine) in chloroform resulted in UV/vis and 1H NMR spectral changes because of complex formation. |
| Keywords: | Alkynes cross-coupling metal complex terpyridines |