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PCC-Promoted Dehydration of Aldoximes: A Convenient Access to Aromatic,Heteroaromatic, and Aliphatic Nitriles
Authors:S Chandrappa  T S R Prasanna  K Vinaya  D S Prasanna
Institution:1. Department of Studies in Chemistry , University of Mysore, Manasagangotri , Mysore , India;2. Synthetic Polymer Laboratory, Department of Polymer Science and Technology , Sri Krisnadevaraya University , Anantapur , India
Abstract:A simple and convenient procedure for the synthesis of nitriles by dehydration of aldoximes using a PCC (pyridiniumchlorochromate) has been developed. A variety of aromatic, heteroaromatic, and aliphatic aldoximes are converted.

Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications® for the full spectral details.

Keywords:Aldoxime  carbonyl group  dehydration  nitrile  oxidizing agent  PCC
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