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Triphenylphosphine-Mediated Synthesis of Methyl 2-Aroyloxypropenoates from 2-Aroyl-2-methoxycarbonyloxiranes
Authors:Eun-Gu Han
Institution:Organic Synthesis Laboratory, Department of Chemical Engineering , Hanyang University , Seoul, Korea
Abstract:A new synthesis of several 2-aroyloxypropenoic acid methyl esters 5 by the reaction of 2-aroyl-2-methoxycarbonyloxiranes 2 with triphenylphosphine in tetrahydrofuran has been described.
Keywords:2-Aroyl-2-methoxycarbonyloxirane  Baylis–Hillman adduct  methyl 2-aroyloxypropenoate  triphenylphosphine
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