The oxysulfenylation of alkenes with dimethyl sulfoxide/oxalyl chloride |
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| Authors: | Yongguo Liu Yang Gao Zhitong Wang Jian Dong Rui Ding Baoguo Sun |
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| Institution: | Beijing Advanced Innovation Center for Food Nutrition and Human Health, Beijing Key laboratory of Flavor Chemistry, Beijing Technology and Business University, Beijing, China |
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| Abstract: | A convenient method for the oxysulfenylation of alkenes using dimethyl sulfoxide/oxalyl chloride is described. Cycloalkenes give trans-adducts stereospecifically. The reactions of styrene are highly regioselective for Markovnikov adducts, whereas aliphatic alkenes lead to anti-Markovnikov adducts mainly. |
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| Keywords: | Alkenes dimethyl sulfoxide oxysulfenylation oxalyl chloride |
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