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Hydrothermal synthesis of ultrathin hexagonal nickel hydroxide nanosheets
Institution:1. Institute of Automotive Engineering, School of Mechanical Engineering, National Engineering Laboratory for Automotive Electronic Control Technology, Shanghai Jiao Tong University, Shanghai 200240, China;2. Institute of Nano Biomedicine and Engineering, Department of Instrument Science and Technology, Key Laboratory for Thin Film and Microfabrication Technology of Ministry of Education, School of Electronic Information and Electrical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China;1. Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, College of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang, Jiangxi, PR China;2. School of Energy and Environmental Engineering, Hebei University of Technology, Tianjin 300130, PR China;3. State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150090, PR China;1. Department of Transdisciplinary Studies, Graduate School of Convergence Science and Technology, Seoul National University, 145 Gwanggyo-ro, Yeongtong-gu, Suwon-si, Gyeonggi-do, 16229, Republic of Korea;2. Department of Applied Biology and Chemical Technology and the State Key Laboratory of Chemical Biology and Drug Discovery, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong Special Administrative Region;3. Research Institute for Smart Energy, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong Special Administrative Region;4. Advanced Institutes of Convergence Technology, 145 Gwanggyo-ro, Yeongtong-gu, Suwon-si, Gyeonggi-do, 16229, Republic of Korea;1. School of Metallurgy, Northeastern University, Shenyang 110819, China;2. Key Laboratory of Ecological Metallurgy of Multi-metal Intergrown Ores of Ministry of Education, Northeastern University, Shenyang 110819, China;1. Shaanxi Engineering Lab for Advanced Energy Technology, School of Materials Science and Engineering, Shaanxi Normal University, Xi’an 710119, PR China;2. State key Laboratory of Catalysis, iChEM, Dalian Institute of Chemical Physics, Dalian National Laboratory for Clean Energy, Chinese Academy of Sciences, Dalian 116023, PR China;3. School of Material Science and Engineering & National Institute for Advanced Materials, Nankai University, Tianjin 30071, PR China
Abstract:Nickel hydroxide, Ni(OH)2 is widely used in electrodes of nickel-based alkaline secondary batteries. Ultrathin hexagonal Ni(OH)2 nanosheets of space group P-3m1 were hydrothermally prepared at 200 °C for 10 h. Their diameter and thickness were 200–300 and 3–5 nm, respectively. Their formation was attributed to the oriented assembly of growing particles, which was assisted by surfactant molecules. The specific surface area of the Ni(OH)2 nanosheets was 8.66 m2/g. Their magnetization curve exhibited linear paramagnetic behavior across the entire measurement region.
Keywords:Hydrothermal method  PEG-200  Paramagnetic behavior
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