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(P, Vm, T) Measurements of (octane + 1-chlorohexane) at temperatures from 298.15 K to 328.15 K and at pressures up to 40 MPa
Affiliation:1. Department of Physics, Acharya Nagarjuna University, Nagarjuna nagar, Guntur 522 510, India;2. Department of Engineering Physics, Gitam Univeristy, Hyderabad campus 502 329, India;3. Department of Chemical Science, Faculty of Science, Universiti Tunku Abdul Rahman, Jalan Universiti, Bandar Barat, 31900 Kampar, Perak, Malaysia
Abstract:
Densities were measured for the liquid octane and 1-chlorohexane, and for nine of their mixtures at four temperatures between 298.15 K and 328.15 K and at pressures up to 40 MPa. An apparatus for density measurements of liquids and liquid mixtures whose main part is a high-pressure vibrating-tube densimeter working in a static mode was used for the measurement. The density data were fitted to the Tait equation and the isothermal compressibilities were calculated with the aid of this equation. Excess molar volumes were also computed from the densities and fitted to the Redlich–Kister equation.
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