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| The reversible addition-fragmentation chain transfer （RAFT） miniemulsion polymerization of vinyl acetate mediated by xanthate | |
| 引用本文： | Bo Jiang,Qing Hua Zhang,Xiao Li Zhan,Feng Qiu Chen. The reversible addition-fragmentation chain transfer （RAFT） miniemulsion polymerization of vinyl acetate mediated by xanthate[J]. 中国化学快报, 2009, 20(6): 733-737. DOI: 10.1016/j.cclet.2008.12.023 |
| 作者姓名： | Bo Jiang Qing Hua Zhang Xiao Li Zhan Feng Qiu Chen |
| 作者单位： | Department of Chemical and Biochemical Engineering, Zhejiang University, Hangzhou 310027, People's Republic of China |
| 摘 要： | The reversible addition-fragmentation chain transfer(RAFT) miniemulsion polymerization of vinyl acetate(VAc) mediated by methyl(methoxycarbonothioyl) sulfanyl acetate(MMSA) was carried out.The results showed that polymerizations initiated by AIBN and KPS proceeded in a controlled way.The RAFT miniemulsion polymerization of VAc initiated by KPS showed the shorter inhibition period,higher propagation rate coefficient and final conversion than those in experiment initiated by AIBN.When the monomer conversio... |
| 关 键 词： | 醋酸乙烯酯 细乳液聚合 链转移反应 介导 断裂 加成 可逆 黄药 |
| 收稿时间： | 2008-10-10 |
The reversible addition-fragmentation chain transfer(RAFT) miniemulsion polymerization of vinyl acetate mediated by xanthate |
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| Bo Jiang,Qing Hua Zhang,Xiao Li Zhan,Feng Qiu Chen. The reversible addition-fragmentation chain transfer(RAFT) miniemulsion polymerization of vinyl acetate mediated by xanthate[J]. Chinese Chemical Letters, 2009, 20(6): 733-737. DOI: 10.1016/j.cclet.2008.12.023 | |
| Authors: | Bo Jiang Qing Hua Zhang Xiao Li Zhan Feng Qiu Chen |
| Affiliation: | Department of Chemical and Biochemical Engineering, Zhejiang University, Hangzhou 310027, People's Republic of China |
| Abstract: | The reversible addition-fragmentation chain transfer (RAFT) miniemulsion polymerization of vinyl acetate (VAt) mediated by methyl (methoxycarbonothioyl) sulfanyl acetate (MMSA) was carried out. The results showed that polymerizations initiated by AIBN and KPS proceeded in a controlled way. The RAFT miniemulsion polymerization of VAc initiated by KPS showed the shorter inhibition period, higher propagation rate coefficient and final conversion than those in experiment initiated by AIBN. When the monomer conversion reached 25%, the polydispersity index (PDI) of polymer became broad, which was related to chain transfer reaction in RAFT miniemulsion of VAc. |
| Keywords: | Vinyl acetate Xanthate Reversible addition-fragmentation chain transfer Miniemulsion |
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