The standard thermodynamic characteristics of resolvation of the K+, Ca2+, Cd2+, and Br− ions in water-acetone mixtures |
| |
| Authors: | T. I. Chankina V. I. Parfenyuk |
| |
| Affiliation: | (1) Institute of the Solution Chemistry, Russian Academy of Sciences, Ivanovo, Russia |
| |
| Abstract: | The standard real and chemical thermodynamic characteristics of transfer of the K+, Ca2+, Cd2+, and Br? ions from water into water-acetone solvents of various compositions were analyzed to study the rules governing the solvation of these ions in mixed solvents and its special features. All calculations were performed within the framework of the vertical jet method at 298.15 K. The energy of resolvation as a function of ion charges and crystallographic radii was found to increase in the series K+ < Ca2+ < Cd2+ < Al3+ |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
