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Diterpenic skeleton transformations : alumina catalysed rearrangements of epoxides |
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| Authors: | Martine Taran Bernard Delmond |
| Affiliation: | Institut du Pin - Université de Bordeaux I 351, cours de la Libération - 33405 TALENCE France |
| Abstract: | The 8,14 β-epoxide of methyl sandaracopimarate undergoes new rearrangements on contact with active alumina, yielding labdane and another compound having the cycloisopimarane skeleton. |
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