| 基于1,10-邻菲罗啉-5,6-二酮和Keggin型多金属氧化物的化合物的水热合成及性质 |
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| 引用本文： | 刘春波,王倩倩,白红叶,车广波,张青,李春香.基于1,10-邻菲罗啉-5,6-二酮和Keggin型多金属氧化物的化合物的水热合成及性质[J].无机化学学报,2013,29(18). |
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| 作者姓名： | 刘春波 王倩倩 白红叶 车广波 张青 李春香 |
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| 作者单位： | 江苏大学化学化工学院, 镇江 212013;江苏大学化学化工学院, 镇江 212013;江苏大学化学化工学院, 镇江 212013;环境友好材料制备与应用教育部重点实验室, 四平 136000;江苏大学化学化工学院, 镇江 212013;江苏大学化学化工学院, 镇江 212013 |
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| 基金项目： | 教育部新世纪优秀人才（NCET-10-0176）和江苏大学自然科学基金（No.11JDG104andBK2011528）资助项目。 |
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| 摘 要： | 在水热条件下，用1，10-邻菲罗啉-5，6-二酮(Do)作为中性配体合成了3个基于Keggin型多金属氧化物的化合物(HDo)6(PW12O40)2·H2O(1)，Cu(Do)2(H2O)]2Cu(Do)2(PW12O40)(H2O)](PW12O40)(2)和Pb(Do)2(PW12O40)](HDo)(3)，并对其进行了元素分析、红外光谱、电感耦合等离子体分析、Ｘ射线光电子能谱、热重分析以及荧光光谱等表征。单晶X射线衍射分析表明化合物1和2为零维结构，化合物3是一维链状结构。
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| 关 键 词： | 1 10-邻菲罗啉-5 6-二酮 Keggin型多金属氧化物 水热 晶体结构 |
Hydrothermal Syntheses and Properties of Compounds Based on 1,10-Phenanthroline-5,6-dione and Keggin-Type Polyoxometalate |
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| LIU Chun-Bo,WANG Qian-Qian,BAI Hong-Ye,CHE Guang-Bo,ZHANG Qing and LI Chun-Xiang.Hydrothermal Syntheses and Properties of Compounds Based on 1,10-Phenanthroline-5,6-dione and Keggin-Type Polyoxometalate[J].Chinese Journal of Inorganic Chemistry,2013,29(18). |
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| Authors: | LIU Chun-Bo WANG Qian-Qian BAI Hong-Ye CHE Guang-Bo ZHANG Qing and LI Chun-Xiang |
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| Institution: | School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China;School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China;School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China;Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Chinese Ministry of Education, Jilin Normal University, Siping, Jilin 136000, China;School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China;School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China |
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| Abstract: | Three compounds based on Keggin-type polyoxometalate (POMs) using1,10-phen-5,6-dione (Do) as neutral organic ligand, namely, (HDo)6(PW12O40)2·H2O (1), Cu(Do)2(H2O)]2Cu(Do)2(PW12O40)(H2O)](PW12O40)(2) and Pb(Do)2(PW12O40)](HDo)(3), have been synthesized under hydrothermal conditions and characterized by elemental analyses, infrared spectra, inductively coupled plasma analyses, X-ray photoelectron spectroscopy and single-crystal X-ray diffraction. Compounds 1 and 2 are zero-dimensional structures, and compound 3 exhibits one-dimensional chain. The thermal stabilities and photoluminescent properties of three compounds have also been investigated. CCDC: 767622, 1; 767623, 2; 767619, 3. |
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| Keywords: | 1 10-phenanthroline-5 6-dione keggin-type polyoxometalate hydrothermal crystal structure |
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