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Mössbauer study on LiFePO4 cathode material for lithium ion batteries
Authors:B. Hannoyer  A. A. M. Prince  M. Jean  R. S. Liu  G. X. Wang
Affiliation:(1) Institut des Matériaux, Université de Rouen, LASTSM, 76801 St. Etienne du Rouvray cedex, France;(2) Department of Chemistry, Madras Christian College, Tambaram, 600 059 Chennai, Tamil Nadu, India;(3) Department of Chemistry, National Taiwan University, Taipei, 106, Taiwan, Republic of China;(4) Institute for Superconducting & Electronic Materials, University of Wollongong, Wollongong, Australia
Abstract:
Crystalline LiFePO4 has been synthesized using solid-state, spray pyrolysis, and wet chemical methods. The crystal parameters were obtained from Rietveld’s refinement methods of the X-ray diffraction patterns. A detailed investigation of the Fe valency carried out using Mössbauer spectroscopy at room temperature indicates that Fe is predominantly present in its bivalent state.
Keywords:lithium-ion batteries  cathode material  M?ssbauer spectroscopy
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