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Solid–liquid equilibria based on an equation of state for chain fluids
Authors:Changjun Peng   Honglai Liu  Ying Hu
Affiliation:

Thermodynamics Research Laboratory, East China University of Science and Technology, 130 Meilong, Shanghai 200237, China

Abstract:Solid–liquid equilibria were studied using an equation of state previously developed for fluids containing chain-like molecules. The method was used to correlate solubilities of normal alkanes and aromatic compounds with high molecular mass in hydrocarbon solvents. With one temperature independent parameter for the interaction energy, good agreement can be obtained between calculated results and experimental data for selected systems.
Keywords:Molecular thermodynamic model   Solid–liquid equilibrium   Solubility   Normal alkane   Aromatic hydrocarbon
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