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Cationic complexes of chelated bis(η-cyclopentadienyl)titanium(IV) with halometallates of gallium(III), indium(III) and thallium(III)
Authors:Kishor K Kakkar  Dinesh C Rupainwar  Ramesh C Srivastava
Institution:(1) Applied Chemistry Section, Institute of Technology, Banaras Hindu University, 221005 Varanasi, India;(2) Chemistry Department, Lucknow University, Lucknow, India
Abstract:Summary Eight complexes of the chelated bis(eegr-cyclopenta-dienyl)titanium(IV) cation. eegr-Cp2TiL]MX4] (L = acetyl-acetone, M = GaIII, InIII or TiIII: X = Cl, Br or I) have been isolated from aqueous solution and characterised by elemental analyses and i.r. data. Their ionic nature has been confirmed by conductance measurements.
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