| COORDINATION POLYMERIZATION OF BENZOTRIAZOLE ON THE SURFACE OF METALLIC COPPER |
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| 作者姓名： | 薛奇 戴庆平 丁建夫 武培怡 |
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| 作者单位： | Department of Chemistry，Nanjing University，Nanjing.，Department of Chemistry，Nanjing University，Nanjing.，Department of Chemistry，Nanjing University，Nanjing.，Department of Chemistry，Nanjing University，Nanjing. |
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| 摘 要： | The coordination polymerization of benzotriazole with metallic copper has been investigated by infrared and X-ray photoelectron spectroscopies. We found that benzotriazole could react with copper (0) under mild conditions to form bis (benzotriazolato) copper (Ⅱ) and benzotriazolato copper (Ⅰ)which covered the surface of copper metal in the shape of polymeric materials. Since benzotriazole is of great interest as a ligand in that its presence in many biological system with metal ions, and is considered as a corrosion inhibitor, this work will be in favour of the study of protective corrosion.
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| 收稿时间： | 1988-06-14 |
COORDINATION POLYMERIZATION OF BENZOTRIAZOLE ON THE SURFACE OF METALLIC COPPER |
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| XUE Gi,DAI Qinpin,DING Jianfu,WU Peiyi.COORDINATION POLYMERIZATION OF BENZOTRIAZOLE ON THE SURFACE OF METALLIC COPPER[J].Chinese Journal of Polymer Science,1989,0(3):239-244. |
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| Authors: | XUE Gi DAI Qinpin DING Jianfu WU Peiyi |
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| Institution: | Department of Chemistry; Nanjing University; Nanjing. |
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| Abstract: | The coordination polymerization of benzotriazole with metallic copper has been investigated by infrared and X-ray photoelectron spectroscopies. We found that benzotriazole could react with copper (0) under mild conditions to form bis (benzotriazolato) copper (Ⅱ) and benzotriazolato copper (Ⅰ)which covered the surface of copper metal in the shape of polymeric materials. Since benzotriazole is of great interest as a ligand in that its presence in many biological system with metal ions, and is considered as a corrosion inhibitor,this work will be in favour of the study of protective corrosion. |
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| Keywords: | Benzotriazole Metallic copper Coordination polymerization on surface Infrared X-ray photoelectron spectroscopy |
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