Untersuchungen über die diamagnetische Suszeptibilität einiger Organo (imino-oxy)silane |
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| Authors: | Goel A. B. Singh A. Mehrotra R. C. |
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| Affiliation: | (1) Chemistry Department, Delhi University, 110007 Delhi, Indien;(2) Present address: Chemistry Department, Rajasthan University, Jaipur, India |
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| Abstract: | Diamagnetic susceptibilities of trimethyl(imino-oxy)silanes,Me3SiON  CMeR, and dimethyldi(imino-oxy)silanes,Me2Si(ON CMeR)2, containing Si–O bonds are reported.  M of these silicon compounds has been calculated theoretically from the method ofBaudet et al. and a good agreement has been obtained between the observed M values and the corresponding calculated values. Si in these compounds has been calculated graphically and the lower values have been explained on the basis of  back-bonding to the silicon atom from the oxygen lone pair. |
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