Synthesis,Structure and Magnetic Properties of dimeric Nickel(II) Benzoate with Pyridyl‐substituted Nitronyl Nitroxides |
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| Authors: | Lili Zhu Xiaodan Chen Qihua Zhao Zhongshu Li Xiangyang Zhang Baiwang Sun Prof. Dr. |
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| Affiliation: | 1. Ordered Matter Science Research Center, Department of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096 P. 2. R. China;3. Department of Chemistry Key Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, Yunan University, Kunming 650091, P. 4. Department of Organic Chemistry, ETH Zurich, 8093 Zurich, Switzerland |
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| Abstract: | The novel heterospin complex [Ni2(PhCOO)4(NITpPy)2]·2CH3CN ( 1 ) was synthesized by the reaction of nickel benzoate and 2‐(4‐pyridyl)‐4,4,5,5‐tetramethylimidazoline‐1‐oxyl‐3‐oxide (NITpPy) in acetonitrile and dichloromethane solutions. The X‐ray structure determination shows that complex 1 consists of a symmetrical dimeric NiII benzoate paddle‐wheel core and pyridyl nitrogen atoms of radical ligands at the apical position, in addition, the temperature (2–300K) dependent magnetic susceptibility measurements indicate that 1 has antiferromagnetic behavior. |
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| Keywords: | Nitronyl nitroxides Radicals Benzoates Magnetic properties Nickel |
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