Hole‐transporting host‐polymer series consisting of triphenylamine basic structures for phosphorescent polymer light‐emitting diodes

A series of novel styrene derived monomers with triphenylamine‐based units, and their polymers have been synthesized and compared with the well‐known structure of polymer of N,N′‐bis(3‐methylphenyl)‐N,N′‐diphenylbenzidine with respect to their hole‐transporting behavior in phosphorescent polymer light‐emitting diodes (PLEDs). A vinyltriphenylamine structure was selected as a basic unit, functionalized at the para positions with the following side groups: diphenylamine, 3‐methylphenyl‐aniline, 1‐ and 2‐naphthylamine, carbazole, and phenothiazine. The polymers are used in PLEDs as host polymers for blend systems with the following device configuration: glass/indium–tin–oxide/PEDOT:PSS/polymer‐blend/CsF/Ca/Ag. In addition to the hole‐transporting host polymer, the polymer blend includes a phosphorescent dopant Ir(Me‐ppy)₃] and an electron‐transporting molecule (2‐(4‐biphenyl)‐5‐(4‐tert‐butylphenyl)‐1,3,4‐oxadiazole). We demonstrate that two polymers are excellent hole‐transporting matrix materials for these blend systems because of their good overall electroluminescent performances and their comparatively high glass transition temperatures. For the carbazole‐substituted polymer (T_g = 246 °C), a luminous efficiency of 35 cd A^?1 and a brightness of 6700 cd m^?2 at 10 V is accessible. The phenothiazine‐functionalized polymer (T_g = 220 °C) shows nearly the same outstanding PLED behavior. Hence, both these polymers outperform the well‐known polymer of N,N′‐bis(3‐methylphenyl)‐N,N′‐diphenylbenzidine, showing only a luminous efficiency of 7.9 cd A^?1 and a brightness of 2500 cd m^?2 (10 V). © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 3417–3430, 2010