Synthesis and solution properties of a pH‐responsive cyclopolymer of zwitterionic ethyl 3‐(N,N‐diallylammonio)propanephosphonate |
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Authors: | Shaikh A Ali N Y Abu‐Thabit Hasan A Al‐Muallem |
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Institution: | Center of Research Excellence in Petroleum Refining & Petrochemicals and Chemistry Department, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia |
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Abstract: | The zwitterionic monomer, ethyl 3‐(N,N‐diallylammonio)propanephosphonate, was cyclopolymerized in aqueous solutions using t‐butylhydroperoxide or ammonium persulfate as initiators to afford a polyphosphonobetaine (PPB). The protonation of P(?O)OEtO– and deprotonation of ? NH+ groups in PPB by HCl and NaOH, gave the corresponding cationic polyphosphononic acid (CPP) and anionic polyphosphonate (APP). The presence of two pH‐responsive functionalities in APP has led to establish the equilibria: APP ? PPB ? CPP, the position of which very much dictates the viscosity behavior of its aqueous solution. The PPB demonstrated “antipolyelectrolyte” viscosity behavior; however, in contrast to many polycarbo‐ and polysulfo‐betaines, it was found to be soluble in salt‐free water as well as in salt‐added solutions. Basicity constant (K1) of the amine group in APP, as determined by potentiometric technique, were found to be “apparent,” and as such followed the modified Henderson‐Hasselbalch equation. The study demonstrated a correlation between the basicity constants and viscosity values. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010 |
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Keywords: | cyclopolymerization polybetaine polyelectrolyte polyphosphonobetaine solution properties water‐soluble polymers |
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