| Synthesis,Crystal Structure and Characterization of a Cobalt Coordination Polymer： [Co（bib）（L）]-0.5H2O |
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| 作者姓名： | WANG Xiu-Yan, NG Seik Weng, WANG Qing-Wei |
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| 作者单位： | WANG Xiu-Yan,WANG Qing-Wei(Department of Chemistry, Jilin Normal University, Siping 136000, China);NG Seik Weng(Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia) |
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| 基金项目： | The project was supported by the Education Office of Jilin Province （No. 0047） |
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| 摘 要： | The title coordination polymer, [Co（bib）（L）].0.5H2O 1 （bib = 1,1＇-（1,4-butanediyl）bis（imidazole） and L = 4,4＇-oxy（bisbenzoate） has been hydrothermally synthesized and characterized by IR and single-crystal X-ray diffraction. It crystallizes in monoclinic, space group Cc with a = 8.8568（5）, b = 19.936（1）, c = 26.209（2） γ, y = 97.510（1）°, V= 4587.8（5） A3, Z = 8, CoC24H23N4O5.5, Mr = 514.39, Dc = 1.489 g/cm3, F（000） = 2128, μ（MoKa） = 0.795 mm^-1, R = 0.0419 and wR = 0.1002. Compound 1 exhibits a rare two-fold interpenetrating CdSO4 type topology. The O-H...O hydrogen bonds stabilize the structure of 1.
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| 关 键 词： | 钴配位聚合物 晶体结构 水热合成 表征 单晶X射线衍射 红外光谱 单斜晶系 俄亥俄州 |
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