[2,6‐Bis(5‐methyl‐2‐pyridyl)phenyl‐κ3N,C1,N′]chloridoplatinum(II) |
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Authors: | Taichi Abe Kazuteru Shinozaki Noriaki Ikeda Takayoshi Suzuki |
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Abstract: | In the title compound, Pt(C18H15N2)Cl], the PtII centre adopts a distorted square‐planar coordination geometry due to the pincer‐type monoanionic N–C–N tridentate ligand. The planar complexes stack viaπ–π interactions to form two‐dimensional accumulated sheets. This packing pattern is in contrast to that in related pincer‐type N–C–N complexes, which exhibit a one‐dimensional columnar stacking. |
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