Bis[bis(methoxycarbimido)amine‐κ2N,N′]bis(perchlorato‐κO)copper(II) bis[bis(methoxycarbimido)amine‐κ2N,N′]bis(methanol‐κO)copper(II) bis(perchlorate) methanol disolvate |
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Authors: | Guang‐Fei Liu Lin‐Lin Li Yong Zhang Jian‐Ping Lang Seik Weng Ng |
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Abstract: | The title compound, Cu(ClO4)2(C4H9N3O2)2]Cu(C4H9N3O2)2(CH4O)2](ClO4)2·2CH3OH, comprises two independent CuII species lying on different inversion sites. In the Cu complexes, a distorted octahedral geometry arises (from basic square‐planar N4 coordination) from the weak coordination of two perchlorate ions (as Cu—O) in one species and two methanol molecules in the other (also as Cu—O). Interactions between the O atoms of the perchlorate anions or methanol groups and the imide or amine NH groups afford an extensive intermolecular hydrogen‐bonding network. |
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