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μ‐{N,N′‐Bis[2‐(dimethyl­amino)ethyl]oxamidato(2–)}‐1κ2O,O′:2κ4N,N′,N′′,N′′′‐bis­(4,4′‐dimethyl‐2,2′‐bipyridine‐1κ2N,N′)dinickel(II) bis­(perchlorate)
Authors:Wei Sun  Yan‐Tuan Li  Zhi‐Yong Wu  Ning‐Yu Xiao
Abstract:In the crystal structure of the title complex, Ni2(C10H20N4O2)(C12H12N2)2](ClO4)2 or Ni(dmaeoxd)Ni(dmbp)2](ClO4)2 {H2dmaeoxd is N,N′‐bis­2‐(dimethyl­amino)ethyl]oxamide and dmbp is 4,4′‐dimethyl‐2,2′‐bipyridine}, the deprotonated dmaeoxd2? ligand is in a cis conformation and bridges two NiII atoms, one of which is located in a slightly distorted square‐planar environment, while the other is in an irregular octa­hedral environment. The cation is located on a twofold symmetry axis running through both Ni atoms. The dmaeoxd2? ligands inter­act with each other via C—H?O hydrogen bonds and π–π inter­actions, which results in an extended chain along the c axis.
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