μ‐{N,N′‐Bis[2‐(dimethylamino)ethyl]oxamidato(2–)}‐1κ2O,O′:2κ4N,N′,N′′,N′′′‐bis(4,4′‐dimethyl‐2,2′‐bipyridine‐1κ2N,N′)dinickel(II) bis(perchlorate) |
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Authors: | Wei Sun Yan‐Tuan Li Zhi‐Yong Wu Ning‐Yu Xiao |
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Abstract: | In the crystal structure of the title complex, Ni2(C10H20N4O2)(C12H12N2)2](ClO4)2 or Ni(dmaeoxd)Ni(dmbp)2](ClO4)2 {H2dmaeoxd is N,N′‐bis2‐(dimethylamino)ethyl]oxamide and dmbp is 4,4′‐dimethyl‐2,2′‐bipyridine}, the deprotonated dmaeoxd2? ligand is in a cis conformation and bridges two NiII atoms, one of which is located in a slightly distorted square‐planar environment, while the other is in an irregular octahedral environment. The cation is located on a twofold symmetry axis running through both Ni atoms. The dmaeoxd2? ligands interact with each other via C—H?O hydrogen bonds and π–π interactions, which results in an extended chain along the c axis. |
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