(Croconato‐κ2O,O′)bis(1,10‐phenanthroline‐κ2N,N′)cobalt(II), and the nickel(II) and copper(II) analogues |
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Authors: | Xia Chen Hong‐Feng Chen Gang Xue Hong‐Yu Chen Wen‐Tao Yu Qi Fang |
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Abstract: | The title complexes, M(C5O5)(C12H8N2)2], with M = CoII, NiII and CuII, all lie across twofold rotation axes, around which two 1,10‐phenanthroline ligands are arranged in a chiral propeller manner. The CoII and NiII complexes are isostructural, with octahedral coordination geometry, while the local geometry of the CuII complex is severely distorted from octahedral. |
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