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Tris(acetyl­acetonato‐κ2O,O′)(1,10‐phenanthroline‐κ2N,N′)erbium(III)
Authors:Gururaj M Neelgund  S A Shivashankar  T Narasimhamurthy  R S Rathore
Abstract:The title compound, Er(C5H7O2)3(C12H8N2)], is a mixed‐ligand metal–organic precursor for chemical vapour deposition, with the Er atom being eight‐coordinate. The coordination polyhedron, described as a distorted square anti­prism, is formed by three bidentate (chelating) acetyl­acetonate residues and a phenanthroline ligand in the apical positions. Mol­ecular assembly via C—H?O hydrogen bonds generates a sheet structure in the ac plane. Weak co‐operative C—H?π inter­actions form mol­ecular dimers and contribute to the stability of the inter­sheet packing. The supra­molecular assembly contains voids which form hydro­phobic porous channels, surrounded by a cluster of dimers.
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