catena‐Poly[[[pyridinecopper(II)]bis[μ3‐4‐(2‐oxidobenzylideneamino)benzoato]] dimethylformamide disolvate], a polymer composed of dimeric dicopper building units |
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Authors: | Qing‐Ling Ni Fa‐Si Li Xiu‐Jian Wang Xian‐Su Bi Sen Liao |
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Abstract: | The title compound, {Cu(C14H9NO3)(C5H5N)]·C3H7NO}n or {Cu2L2(py)2]·2DMF}n py is pyridine, L is 4‐(salicylideneamino)benzoate and DMF is dimethylformamide], is composed of dimeric dicopper CuL(py)]2 building units, which are interlinked into a one‐dimensional chain through the formation of Cu—OCOO bonds. The dimeric unit is centrosymmetric, containing two CuII atoms linked by bridging phenolate O atoms into a Cu2O2 plane with a chelating Cu—O bond length of 1.927 (2) Å and a bridging Cu—O bond length of 2.440 (2) Å. Interchain C—H...O and π–π stacking interactions are responsible for an extensive three‐dimensional structure in which the resulting channels are filled by DMF solvent molecules. |
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