Synthesis of chiral chromium tricarbonyl labeled thymine PNA monomers via the Ugi reaction |
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| Authors: | Baldoli Clara Maiorana Stefano Licandro Emanuela Zinzalla Giovanna Perdicchia Dario |
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| Affiliation: | CNR Istituto di Scienze e Tecnologie Molecolari e Dipartimento di Chimica Organica e Industriale, University of Milan, Via C. Golgi 19, I-20133 Milano, Italy. |
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| Abstract: | ![]()
[reaction: see text] Ugi condensation was used to synthesize the first examples of chiral racemic Ar.Cr(CO)(3) labeled peptide nucleic acid (PNA) monomers bearing the organometallic moiety linked to the alpha-carbon of the glycine unit. |
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