The rotational predissociation of the CH4+ and CD4+ ions |
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| Authors: | JP Flamme H Wankenne R Locht J Momigny PJCM Nowak J Los |
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| Institution: | Institut de Chimie, Département de Chimie Générale et de Chimie Physique, Sart Tilman par B-4000 Liège I, Belgium;FOM-Instituut voor Atoom- en Molekuulfysica, Amsterdam/Wgm, The Netherlands |
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| Abstract: | The metastable transitions producing CH33/CH4 and CD3+/CD4 have been investigated by means of translational spectroscopy. For the first time structures are observed in a metastable peak corresponding to the dissociation of a polyatomic ion. They are interpreted by tunneling through a rotational barrier from discrete quasi-bound states. Kinetic energy releases have been measured. |
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