Regioselective Benzoylation of Glycopyranosides by Benzoyl Chloride in the Presence of MoO2(acac)2 |
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| Authors: | E. V. Evtushenko |
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| Affiliation: | Pacific Institute of Bioorganic Chemistry, Far East Branch of the Russian Academy of Sciences , Vladivostok, Russia |
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| Abstract: | Benzoylation of methyl and benzyl glycopyranosides by benzoyl chloride in the presence of MoO2(acac)2 as a catalyst resulted in 3-benzoates with good yield and high regioselectivity. Simple synthesis of the monobenzoates of some glycopyranosides is suggested. |
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| Keywords: | Glycopyranosides Regioselective benzoylation Molybdenum |
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