Enzymatic Glycosylation of Branched Symmetrical Non-Carbohydrate Polyols |
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| Authors: | Christoffer Kieburg Thisbe K Lindhorst Vladimír Křen |
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| Institution: | 1. Department of Organic Chemistry , University of Hamburg , Martin-Luther-King-Platz 6, D-20146, Hamburg, Germany;2. Institute of Microbiology, Laboratory of Biotransformation , Academy of Sciences of the Czech Republic , Vídeňská 1083, CZ-142 20, Prague, Czech Republic |
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| Abstract: | Abstract Three glycosidases, α-mannosidase from Jack beans, β-galactosidase from Aspergillus oryzae and β-N-acetylhexosaminidase from Aspergillus oryzae were evaluated for their ability to catalyze the glycosylation of non-saccharidic polyols. A series of monoglycosylated derivatives of tris(2-aminoethyl)cyanuric acid, pentaerythritol and bis(hydroxymethyl)benzene were obtained in pure form and characterized by NMR-spectroscopy. |
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