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A Chemical Synthesis of 3-Deoxy-D-manno-2-octulosonic Acid from D-mannose |
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| Authors: | Tsuyoshi Ichiyanagi Naoko Sakamoto Kazutoshi Ochi Ryohei Yamasaki |
| Affiliation: | Department of Bioresource Sciences , Tottori University , Tottori, 680-8553, Japan |
| Abstract: | A chemical synthesis of Kdo was achieved via the condensation of a protected D-mannofuranose-5,6-cyclic sulfate with ethyl 1,3-dithiane-2-carboxylate, which is an efficient equivalent for installing an α-ketoester unit as a key step. |
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