Eine Einfache Synthese von N-Acyl-Glykosylaminen |
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| Authors: | Almuth Klemer Michael Kohla |
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| Affiliation: | Organisch-Chemisches Institut der Westfalischen Wilhelms-Universitat Munster , Orléans-Ring 23, D-4400, Munster, Fed. Rep. Germany |
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| Abstract: | Abstract D-Ribose, D-arabinose and D-glucose react with nitriles in liquid hydrogen fluoride to give the corresponding 1,2-cis configurated N-acyl-pento (or hexo) furanosyl amines 1-7 and 9. D-Xylose gives the ct-pyranosyl isomer 8 beside the α-furanosyl main product 7. D-Mannose and L-rhamnose yield the N-acyl-α-hexopyranosyl amines 10 and 11. |
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