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激光诱导击穿光谱在塑料分类中的应用
引用本文:Liu K,Wang QQ,Zhao H,Xiao YL. 激光诱导击穿光谱在塑料分类中的应用[J]. 光谱学与光谱分析, 2011, 31(5): 1171-1174. DOI: 10.3964/j.issn.1000-0593(2011)05-1171-04
作者姓名:Liu K  Wang QQ  Zhao H  Xiao YL
作者单位:北京理工大学光电学院,北京,100081
摘    要:利用波长为266 nm紫外激光器获得四大类塑料样品(HDPE,LDPE,PET,NYLON)的诱导击穿等离子光谱(波长范围652~780 nmn),以NIST原子发射谱线数据库作为参考,对其中的主要元素特征谱线进行标定.采用化学计量学中的主成分分析法对光谱数据进行处理,并通过交互验证法建立样品的主成分分析模型,分析主成...

关 键 词:主成分  激光诱导击穿光谱  塑料  分类

Differentiation of plastic with laser induced breakdown spectroscopy
Liu Kai,Wang Qian-qian,Zhao Hua,Xiao Yin-long. Differentiation of plastic with laser induced breakdown spectroscopy[J]. Spectroscopy and Spectral Analysis, 2011, 31(5): 1171-1174. DOI: 10.3964/j.issn.1000-0593(2011)05-1171-04
Authors:Liu Kai  Wang Qian-qian  Zhao Hua  Xiao Yin-long
Affiliation:College of Optoelectronics, Beijing Institute of Technology, Beijing 100081, China. liukai1105@yahoo.com.cn
Abstract:The present article investigated the laser induced breakdown spectroscopy for a wide range of plastic (HDPE, LDPE, PET, NYLON) with the ultraviolet (UV) excitation wavelength. Compared with the National Institute of Standards and Technology atomic spectroscopy database line data, the author analyzed the detailed spectral atomic lines of the dominated elements. With the help of principal component analysis in the Chemometrics, the identification model was constructed under the method of cross-validation. Besides, all kinds of potential influence were analyzed for the detailed model. The result showed us vividly that the laser induced breakdown spectroscopy combined with the principal component analysis had the capacity to discriminate different plastic materials. It gave us a new method for model building and material discrimination. These results can be useful for further research on laser induced breakdown spectroscopy for the differentiation of different materials.
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