Effect of pressure and temperature on electrolyte conductance in 2-propanol |
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Authors: | S. L. Wellington D. F. Evans |
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Affiliation: | 1. Shell Development Corporation, P. O. Box 481, 77001, Houston, TX 2. Department of Chemical Engineering and Materials Science, University of Minnesota, 55455, Minneapolis, MN
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Abstract: | ![]() Equivalent conductances for tetrabutylammonium chloride, bromide, iodide, and perchlorate and lithium chloride were determined in 2-propanol at 10, 25, and 40°C over the pressure range 1 to 3,000 kg-cm?2. The data are analyzed with the 1975 Fuoss-Onsager equation. The limiting equivalent conductances and association constants show the same level of precision as generally obtained in high precision conductance measurements at 1 atmosphere. The unusual association pattern observed for electrolytes in alcohols persisted up to the highest pressures used in this study. |
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