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Synthesis, thermal and magnetic properties of new metal iodate: (LiFe1/3)(IO3)2
Authors:Y C Lan  X L Chen  A Y Xie  P Z Jiang and C L Lin
Institution:

a Institute of Physics and Centre for Condensed Matter Physics, Chinese Academy of Sciences, Beijing 100080, People's Republic of China

b Department of Physics, Temple University, Philadelphia, PA 19122, USA

Abstract:This paper reports the detail synthesis of a new kind of metal iodate, anhydrous (LiFe1/3)(IO3)2, from aqueous solutions. The synthesized compound shows spinal morphology and is chemical stable up to 400°C. The iodate shows paramagnetic behavior from room temperature down to 4.2 K. At room temperature, the new compound has a hexagonal structure with the lattice parameters a=5.4632(2) Å, c=5.0895(6) Å, Z=1, space group of P63.
Keywords:A1  Characterization  A2  Growth from solution  B1  Iodate
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