Complexation of Chlorodiethylenetriaminegold(III) with Chloride Ions in Aqueous Solutions |
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Authors: | E V Makotchenko V I Malkova |
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Institution: | (1) Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 3, Novosibirsk, 630090, Russia |
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Abstract: | The reaction of Au(Dien)Cl2+ (Dien is diethylenetriamine) with the chloride ion was studied spectrophotometrically in an aqueous solution at I = 1.0 mol/l and T = 20°C. The formation constant of pentacoordinated Au(Dien)Cl 2 + was determined and its spectrum was calculated. |
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