Catalytic, Regiospecific End-Functionalization of Alkanes: Rhenium-Catalyzed Borylation under Photochemical Conditions期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Catalytic, Regiospecific End-Functionalization of Alkanes: Rhenium-Catalyzed Borylation under Photochemical Conditions

Authors:	Chen Hartwig

Affiliation:	Department of Chemistry, Yale University, P.O. Box 208107, New Haven, CT 06520-8107 (USA).

Abstract:	Approaching a Holy Grail? A regioselective functionalization of alkanes occurs with commercially available rhenium catalysts and borane reagents under photochemical conditions [Eq. (1)]. Mechanistic studies indicate that the regioselectivity results from a direct thermal reaction of a photochemically generated 16-electron boryl complex with alkane.

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