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On the existence of tetragonally deformed octahedrons in the cubic part of the system MnxFe3-xO4
Authors:L. červinka
Affiliation:(1) Institute of Solid State Physics, Czechosl. Acad. Sci., Prague, Cukrovarnická 10, Praha 6
Abstract:
The mean square amplitude of lattice vibrations
$$overline {u^2 } $$
has been measured in the cubic part of the MnxFe3-xO4-system. The observed increase of the
$$overline {u^2 } $$
-value with increasing content of Mn ions in the system is interpreted as that, with gradual occupation of more and more octahedral sites by Mn3+ ions towards higher values ofx, the number of locally distorted Mn3+O62– octahedrons increases.
Keywords:
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