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Thermodynamic quantities for the interaction of SO 4 2− with H+ and Na+ in aqueous solution from 150 to 320°C
Authors:J. L. Oscarson  R. M. Izatt  P. R. Brown  Z. Pawlak  S. E. Gillespie  J. J. Christensen
Affiliation:1. Departments of Chemistry and Chemical Engineering, Brigham Young University, 84602, Provo, UT
Abstract:
The aqueous reactions,

$$begin{gathered}  H^ +   + SO_4^{2 - }  = HSO_4^ -  ,Na^ +   + SO_4^{2 - }  = NaSO_1^ -  , hfill           and H^ +   + HSO_4^ -   = H_2 SO_4 (aq) hfill  end{gathered} $$
Keywords:Equilibrium constant  enthalpy change  entropy change  heat  capacity change  flow calorimetry  high temperature  hydrogen sulfate ion and sodium sulfate ion formation  isocoulombic effect
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