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含碳能源直接制氢的热力学分析与实验研究
引用本文:闫跃龙,肖云汉,田文栋,王峰.含碳能源直接制氢的热力学分析与实验研究[J].工程热物理学报,2003,24(5):744-746.
作者姓名:闫跃龙  肖云汉  田文栋  王峰
作者单位:中国科学院工程热物理研究所,北京,100080
基金项目:国家重点基础研究发展规划项目(No.G1999022301)
摘    要:本文在对构建的含碳能源直接制氢体系进行热力学分析的基础上,建造了含碳能源直接制氢近零排放定容实验系统,并进行了不同参数下的实验研究。热力学分析表明本文构建的系统不仅存在合适的反应条件,而且在此反应条件下可以实现体系的热平衡。实验结果表明了该系统的可行性,实现了气态产物中氢含量大于80%,二氧化碳及一氧化碳含量均小于0.1%,达到了直接制氢和近零排放的目标。

关 键 词:含碳能源  直接制氢  CO_2吸收  近零排放
文章编号:0253-231X(2003)05-0744-03
修稿时间:2002年12月29

THERMODYNAMIC ANALYSIS AND EXPERIMENTAL RESEARCH ON DIRECT HYDROGEN PRODUCTION FROM CARBONACEOUS ENERGY
YAN Yue-Long XIAO Yun-Han TIAN Wen-Dong WANG Feng.THERMODYNAMIC ANALYSIS AND EXPERIMENTAL RESEARCH ON DIRECT HYDROGEN PRODUCTION FROM CARBONACEOUS ENERGY[J].Journal of Engineering Thermophysics,2003,24(5):744-746.
Authors:YAN Yue-Long XIAO Yun-Han TIAN Wen-Dong WANG Feng
Abstract:On the base of thermodynamic analysis of the system of direct hydrogen production from carbonaceous energy, this paper build up a constant volume experimental apparatus, and carried out experimental studies with different parameters. The thermodynamic analysis showed that not only the proper reaction conditions exist but also the thermal equilibrium can be realized. The experimental results showed that the system is feasible, and the direct hydrogen from coal and nearly zero emission are realized; the hydrogen is more than 80% and CO and CO2 are both less than 0.1%.
Keywords:carbonaceous energy  direct hydrogen production  CO2 absorption  nearly zero emission
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