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Development and thermal behaviour of ternary PLA matrix composites
Authors:E. Fortunati  I. Armentano  J.M. Kenny
Affiliation:a Materials Engineering Centre, UdR INSTM, NIPLAB, University of Perugia, Terni, Italy
b Institute of Polymer Science and Technology, CSIC, Juan de la Cierva 3, 28006 Madrid, Spain
Abstract:
Biodegradable PLA composites were prepared using microcrystalline cellulose (MCC) and silver (Ag) nanoparticles. The main objective of the present study is to develop new biopolymer composites with good mechanical properties, thermal stability, maintaining the optical transparency and also providing antimicrobial properties through silver nanoparticle introduction. Composites were prepared with 1%wt of Ag nanoparticles and 5%wt of MCC using a twin-screw microextruder; film parameters were optimized in order to obtain a thickness range between 20 and 60 μm.PLA composites maintained optical transparency properties of the matrix, while MCC was able to reduce polymer permeability. Thermal analysis revealed that MCC increased PLA crystallinity and the mechanical properties of the composites demonstrated that tensile modulus was improved by microcrystalline cellulose.
Keywords:Poly(l-lactide acid)   Microcrystalline cellulose   Silver nanoparticles   Mechanical properties   Thermal properties   Barrier properties
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