Viscosity-change-induced density fingering in polyelectrolytes |
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Authors: | Rica Tamás Horváth Dezsö Tóth Agota |
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Institution: | Department of Physical Chemistry, University of Szeged, Szeged, Hungary. |
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Abstract: | We have studied the density fingering of an acid-catalyzed autocatalytic reaction in the presence of carboxylate containing polyelectrolyte. The decrease in viscosity as a result of the change in the ionic character of the polymer due to the pH-change during the reaction is the major driving force for the spatiotemporal pattern formation. The front evolution is quantitatively characterized by dispersion curves. |
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