The interaction of liquid ammonia and urea and thiourea complexes of copper(I) and (II), silver(I), zinc(II), nickel(II) and palladium(II) |
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| Affiliation: | 1. Department of Chemistry, Dartmouth College, 6128 Burke Laboratory, Hanover, NH 03755, United States;2. Department of Chemistry, University of Maine, Orono, ME 04469, United States;3. Department of Chemistry, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA 92093, United States;1. Institute of Applied Technology, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230088, PR China;2. University of Science and Technology of China, Hefei 230026, PR China;1. Institute of High-Temperature Electrochemistry UB RAS, Ekaterinburg, Russia;2. College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin, China;1. School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024, PR China;2. School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, PR China;3. State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, PR China;4. Department of Physics, BUITEMS, Quetta 87300, Pakistan |
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| Abstract: | The following complexes have been shown to react with anhydrous liquid ammonia by ligand substitution to form the corresponding ammines: Cu(ur)Cl2, Ag(ur)NO3, Zn(tu)Cl2, Ni(tu)4Cl2, Pd(tu)4Cl2. The reactions of the complexes Cu(tu)Cl, Cu(tu)3Cl, Ag(tu)3NO3, and Pd(tu)4Cl2 involve deprotonation and/or conversion of the tu ligand to other species. |
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