Sulfinimine-mediated asymmetric synthesis of beta-hydroxy alpha-amino phosphonates |
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| Authors: | Davis Franklin A Prasad Kavirayani R |
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| Affiliation: | Department of Chemistry, Temple University, Philadelphia, Pennsylvania 19122, USA. fdavis@temple.edu |
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| Abstract: | ![]()
The addition of potassium dialkyl phosphites to enantiopure O-protected alpha-hydroxy sulfinimine pseudoenantiomers affords beta-hydroxy alpha-amino phosphonates in good yield and de. The reaction exhibits a strong match-mismatch effect. |
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