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A highly efficient stereoselective synthesis of (Z)- and (E)-allyl iodides from Baylis-Hillman adducts |
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| Authors: | Biswanath Das Anjoy Majhi Joydeep Banerjee Nikhil Chowdhury Katta Venkateswarlu |
| Affiliation: | Organic Chemistry Division-I, Indian Institute of Chemical Technology, Hyderabad 500007, India |
| Abstract: | A highly efficient synthesis of (Z)- and (E)-allyl iodides has been accomplished by treatment of Baylis-Hillman adducts with iodine and triphenylphosphine in methylene chloride at room temperature. The method is associated with mild reaction conditions, high yields and excellent stereoselectivity. |
| Keywords: | Baylis-Hillman adduct (Z)- and (E)-allyl iodides I2/PPh3 Stereochemistry |
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