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New aromatic annulation reaction via a C14 enaminone synthon: synthesis of ‘terpenoid-like chalcones’
Authors:Alain Valla,Benoist Valla,Ré  gis Le Guillou,Pierre Potier
Affiliation:a Laboratoire de Chimie et Biologie des Substances Naturelles, FRE 2125 CNRS 6, rue de l’Université, 29000 Quimper, France
b Institut de Chimie des Substances Naturelles, avenue de la Terrasse, 91198 Gif-sur-Yvette Cedex, France
Abstract:
Diverse functionalized synthons from a new enaminone are reported. These synthons were easily obtained in a one pot process starting from a compound derived from β-ionone. A new annulation reaction of this C-14 compound with several anions led to new ‘terpenoid-like’ chalcones.
Keywords:Annulation   Enaminones   Salicylates   Terpenoid-like chalcones
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