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Microstructure and photoluminescence of a-SiO x :H
Authors:Zhixun Ma  Xianbo Liao  Wenchao Cheng  Jie He  Guozhen Yue  Yongqian Wang  Guanglin Kong
Affiliation:(1) State Laboratory for Surface Physics, Institute of Semiconductors, Center for Condensed Matter Physics, Chinese Academy of Science, 100083 Beijing, Chinai;(2) State Laboratory for Superlattices and Microstructures, Institute of Semiconductors, Chinese Academy of Sciences, 100083 Beijing, China
Abstract:
Two strong photoluminescence (PL) bands in the spectral range of 550–900 nm have been observed at room temperature from a series of a-SiO x :H films fabricated by plasma-enhanced chemical vapor deposition (PECVD) technique. One is composed of a main band in the red-light region and a shoulder; the other is located at about 850 nm, only found after 1170°C annealing in N2 atmosphere. In conjunction with infrared (IR) and micro-Raman spectra, it is thought that the two PL bands are associated with a-Si clusters in the SiO x network and nanocrystalline silicon in SiO2, respectively. Project supported by the National Natural Science Foundation of China (Grant No. 69576025).
Keywords:quantum confinement effects  photoluminescence  Infrared and Raman spectra
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