| Synthesis and Structureof［（C_2H_5）_4N］［Mo_3（μ_3－O）（μ－Cl）_3（μ－CH_3CH_2COO）_3Cl_3］ |
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| 作者姓名： | Zhuang Hong-Hui Wu Ding-Ming Huang Jian-Quan Huang Jin-Ling |
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| 作者单位： | State Key Laboratory of Structural Chemistry and Fujitan Institute of Research on the Structure of Matter，Chinese Academy of Sciences，Fujian 350002 |
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| 摘 要： | ＳｙｎｔｈｅｓｉｓａｎｄＳｔｒｕｃｔｕｒｅｏｆ［（Ｃ_２Ｈ_５）_４Ｎ］［Ｍｏ_３（μ_３－Ｏ）（μ－Ｃｌ）_３（μ－ＣＨ_３ＣＨ_２ＣＯＯ）_３Ｃｌ_３］ＺｈｕａｎｇＨｏｎｇ－Ｈｕｉ；ＷｕＤｉｎｇ－Ｍｉｎｇ；ＨｕａｎｇＪｉａｎ－Ｑｕａｎ；ＨｕａｎｇＪｉｎ－Ｌ...
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Synthesis and Structure of [(C_2H_5)_4N][Mo_3 (μ_3-O) (μ-Cl)_3(μ-CH_3CH_2COO)_3Cl_3] |
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| Zhuang Hong-Hui, Wu Ding-Ming, Huang Jian-Quan, Huang Jin-Ling.Synthesis and Structure of [(C_2H_5)_4N][Mo_3 (μ_3-O) (μ-Cl)_3(μ-CH_3CH_2COO)_3Cl_3][J].Chinese Journal of Structural Chemistry,1996(4). |
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| Authors: | Zhuang Hong-Hui Wu Ding-Ming Huang Jian-Quan Huang Jin-Ling |
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| Abstract: | The title cluster compound, Mo_3Cl_6O_7NC_17H)35, has been synthesized reaction of a mixture of MoC_l3·3H_2O、(C_3H_5)_4NI and CH_3CH_2COOH. Crystallographic data: monoclinic, space group P2_1/a, a=12. 990 (2), b=19. 572 (5), c =12. 411 (3)A, β=90. 00(4)°, V=3155. 3 A￣3, Z=4, M_r=866. 01, D_c= 1. 823 g/cm￣3. μ(MoKα)=16. 934, MoKα(λ=0. 71073 A ), T= 295K , F(000)=1712, final R=0. 048 and R_w= 0. 062 for 2997 reflections with I≥3σ(I). The crystal contains discrete cations and anions. The mono-oxo-capped trinuclear Mo cluster anion consists of three Cl atoms and three CH_3CH_2COO- groups that bridge the three edges of Mo triangle,and three terminal Cl atoms. The coordination around Mo is distortedly octahedral. |
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| Keywords: | Mo cluster crystal structure synthesis |
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