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CF3Br的红外光化学和光物理
引用本文:林桦,谢匡吉,钱汝麟,穆国融,李长林.CF3Br的红外光化学和光物理[J].物理化学学报,1988,4(1):92-97.
作者姓名:林桦  谢匡吉  钱汝麟  穆国融  李长林
作者单位:Laser Chemistry Laboratory; Fudan University; Shanghai
摘    要:

收稿时间:1986-07-18
修稿时间:1987-04-03

INFRARED PHOTOCHEMISTRY AND PHOTOPHYSICS OF CF3Br
Lin Hua,Xie Kuangjie,Qian Rulin,Mu Ouorong,Li Changlin.INFRARED PHOTOCHEMISTRY AND PHOTOPHYSICS OF CF3Br[J].Acta Physico-Chimica Sinica,1988,4(1):92-97.
Authors:Lin Hua  Xie Kuangjie  Qian Rulin  Mu Ouorong  Li Changlin
Institution:Laser Chemistry Laboratory; Fudan University; Shanghai
Abstract:We present the optothermal and optoacoustic spectra of CF_3Br in TEA CO_2 laser 00°1—02°0 R branch. Three absorption peaks has been observed at R(14) line (1074.6 cm~(-1)), R(18) line (1077.3cm~(-1)), and R(22) line (1079.9cm~(-1)) respectively. The peak at R(22) coincides with the position of P branch of CF_3Br linear IR spectrum, but two peaks at R(14) and R(18) can be interpreted as the hot bands.We also studied the multiphoton dissociation of CF_3Br and carbon isotope seperation.
Keywords:
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